Chlorinated Spiroconjugated Fused Extended Aromatics for Multifunctional Organic Electronics. Issue 12 (15th February 2021)

• Record Type: Journal Article
• Authors: Meng, Dong; Wang, Rui; Lin, Janice B.; Yang, Jonathan Lee; Nuryyeva, Selbi; Lin, Yu‐Che; Yuan, Shuai; Wang, Zhao‐Kui; Zhang, Elizabeth; Xiao, Chengyi; Zhu, Danlei; Jiang, Lang; Zhao, Yepin; Li, Zhenxing; Zhu, Chenhui; Houk, Kendall N.; Yang, Yang
• Is Part Of: Advanced materials. Volume 33:Issue 12(2021)
• Page Start: n/a
• Page End: n/a
• Publication Date: 2021-02-15
• Subjects: chlorination -- fused ring -- organic light‐emitting diode -- organic solar cell -- single‐crystal transistor -- spiroconjugation; Materials -- Periodicals; Chemical vapor deposition -- Periodicals; 620.11
• DOI: 10.1002/adma.202006120
• Languages: English
• ISSNs: 0935-9648

Abstract

Abstract: The synthesis of a new molecule, SFIC‐Cl, is reported, which features enhanced π‐electron delocalization by spiroconjugation and narrowed bandgap by chlorination. SFIC‐Cl is integrated into a single‐crystal transistor (OFET) and organic light‐emitting diode (OLED). The material demonstrates remarkable transport abilities across various solution‐processed OFETs and retains efficient radiance in a near‐infrared OLED emitting light at 700 nm. Furthermore, the intermolecular multi‐dimensional connection of SFIC‐Cl enables the fabrication of a single‐component large‐area (2 × 2 cm 2 ) near‐infrared OLED by spin‐coating. The SFIC‐Cl‐acceptor‐based solar cell shows excellent power conversion efficiency of 10.16% resulting from the broadened and strong absorption and well‐matched energy levels. The study demonstrates that chlorinated spiroconjugated fused systems offer a novel direction toward the development of high‐performance organic semiconductor materials for hybrid organic electronic devices. Abstract : A new molecule, SFIC‐Cl, featured by enhanced π‐electron delocalization by fused‐spiroconjugation and narrowed bandgap by chlorination, is constructed, and is integrated into single‐crystal transistors, organic light‐emitting diodes, and organic photovoltaics. This study demonstrates that these chlorinated spiroconjugated fused systems offer a novel direction toward development of high‐performance organic semiconductor materials for hybrid organic electronic devices.