Integration of metallacycles and polyoxometalate macrocycles. Issue 5 (13th January 2021)

• Record Type: Journal Article
• Authors: Zhu, Zeng-Kui; Lin, Ya-Yun; Li, Xin-Xiong; Zhao, Dan; Zheng, Shou-Tian
• Is Part Of: Inorganic chemistry frontiers. Volume 8:Issue 5(2021)
• Page Start: 1297
• Page End: 1302
• Publication Date: 2021-01-13
• Subjects: Chemistry, Inorganic -- Periodicals; 546.05
• DOI: 10.1039/d0qi01293a
• Languages: English
• ISSNs: 2052-1553

Abstract

Abstract : A series of polyoxometalate–metallacycle composite macrocycles with interesting bi/tri-layer cyclic structures have been synthesized, which show a remarkable integration of metallacycles and polyoxometalate macrocycles at molecular level. Abstract : We demonstrate a remarkable integration of metallacycles and polyoxometalate (POM) macrocycles at the molecular level, forming a series of unprecedented organic–inorganic hybrid POM–metallacycle composite macrocycles with interesting bi-layer and tri-layer cyclic structures, as well various compositions, nuclearities, geometries, and sizes. These molecular composite macrocycles show a fusion of metallacycle and POM chemistry, which opens new perspectives for developing brand-new ring-shaped composite materials.