Spin density localization and accessibility of organic radicals affect liquid-state DNP efficiency. Issue 8 (18th February 2021)
- Record Type:
- Journal Article
- Title:
- Spin density localization and accessibility of organic radicals affect liquid-state DNP efficiency. Issue 8 (18th February 2021)
- Main Title:
- Spin density localization and accessibility of organic radicals affect liquid-state DNP efficiency
- Authors:
- Levien, Marcel
Reinhard, Maik
Hiller, Markus
Tkach, Igor
Bennati, Marina
Orlando, Tomas - Abstract:
- Abstract : Scalar liquid DNP performance scales of a factor ∼5 depending on the spin density distribution and accessibility of the radical. Abstract : We report a large variation in liquid DNP performance of up to a factor of about five in coupling factor among organic radicals commonly used as polarizing agents. A comparative study of 1 H and 13 C DNP in model systems shows the impact of the spin density distribution and accessibility of the radical site by the target molecule.
- Is Part Of:
- Physical chemistry chemical physics. Volume 23:Issue 8(2021)
- Journal:
- Physical chemistry chemical physics
- Issue:
- Volume 23:Issue 8(2021)
- Issue Display:
- Volume 23, Issue 8 (2021)
- Year:
- 2021
- Volume:
- 23
- Issue:
- 8
- Issue Sort Value:
- 2021-0023-0008-0000
- Page Start:
- 4480
- Page End:
- 4485
- Publication Date:
- 2021-02-18
- Subjects:
- Chemistry, Physical and theoretical -- Periodicals
541.3 - Journal URLs:
- http://pubs.rsc.org/en/journals/journalissues/cp#!issueid=cp016040&type=current&issnprint=1463-9076 ↗
http://www.rsc.org/ ↗ - DOI:
- 10.1039/d0cp05796g ↗
- Languages:
- English
- ISSNs:
- 1463-9076
- Deposit Type:
- Legaldeposit
- View Content:
- Available online (eLD content is only available in our Reading Rooms) ↗
- Physical Locations:
- British Library DSC - 6475.306000
British Library DSC - BLDSS-3PM
British Library STI - ELD Digital store - Ingest File:
- 15972.xml