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Post-synthetic modification of a highly flexible 3D soft porous metal–organic framework by incorporating conducting polypyrrole: enhanced MOF stability and capacitance as an electrode material. Issue 20 (8th February 2021)
Record Type:
Journal Article
Title:
Post-synthetic modification of a highly flexible 3D soft porous metal–organic framework by incorporating conducting polypyrrole: enhanced MOF stability and capacitance as an electrode material. Issue 20 (8th February 2021)
Main Title:
Post-synthetic modification of a highly flexible 3D soft porous metal–organic framework by incorporating conducting polypyrrole: enhanced MOF stability and capacitance as an electrode material
Abstract : Porous, stable and functional MOF polymer hybrids can be prepared by the in situ polymerization of otherwise unstable soft crystals. Abstract : Post-synthetic modification of a dynamic carborane-based soft porous crystal (1 ⊃ DMF ) by in situ polymerization of pyrrole to polypyrrole (PPy) provided a permanently porous MOF/polypyrrole hybrid composite material that did not show the dynamic behavior of the mother MOF. Apart from stability, the introduction of conductive PPy in the composite material brings new properties to the otherwise non-conductive MOF.