BNB-doped phenalenyls – aromaticity switch upon one-electron reduction. Issue 19 (5th February 2021)
- Record Type:
- Journal Article
- Title:
- BNB-doped phenalenyls – aromaticity switch upon one-electron reduction. Issue 19 (5th February 2021)
- Main Title:
- BNB-doped phenalenyls – aromaticity switch upon one-electron reduction
- Authors:
- Crumbach, Merian
Ayhan, Ozan
Fritze, Lars
Sprenger, Jan A. P.
Zapf, Ludwig
Finze, Maik
Helten, Holger - Abstract:
- Abstract : Fully aromatic, fluorescent, and highly robust BNB-doped phenalenyls were prepared via ring expansion, which undergo an aromaticity switch upon reduction. Abstract : Fully aromatic, luminescent, and highly robust BNB-doped phenalenyls have been prepared, which are isoelectronic to the phenalenyl cation. B -Fluoromesityl-substitution leads to fluorescence in an extremely narrow range and significant increase in the reduction potential. Detailed theoretical investigations revealed an intramolecular aromaticity switch upon one-electron reduction.
- Is Part Of:
- Chemical communications. Volume 57:Issue 19(2021)
- Journal:
- Chemical communications
- Issue:
- Volume 57:Issue 19(2021)
- Issue Display:
- Volume 57, Issue 19 (2021)
- Year:
- 2021
- Volume:
- 57
- Issue:
- 19
- Issue Sort Value:
- 2021-0057-0019-0000
- Page Start:
- 2408
- Page End:
- 2411
- Publication Date:
- 2021-02-05
- Subjects:
- Chemistry -- Periodicals
540 - Journal URLs:
- http://pubs.rsc.org/en/journals/journalissues/cc ↗
http://www.rsc.org/ ↗ - DOI:
- 10.1039/d0cc07671f ↗
- Languages:
- English
- ISSNs:
- 1359-7345
- Deposit Type:
- Legaldeposit
- View Content:
- Available online (eLD content is only available in our Reading Rooms) ↗
- Physical Locations:
- British Library DSC - 3139.350000
British Library DSC - BLDSS-3PM
British Library STI - ELD Digital store - Ingest File:
- 15976.xml