Mechanical switching of orientation-related photoluminescence in deep-blue 2D layered perovskite ensembles. Issue 7 (15th February 2021)

• Record Type: Journal Article
• Authors: Dhanabalan, Balaji; Castelli, Andrea; Ceseracciu, Luca; Spirito, Davide; Di Stasio, Francesco; Manna, Liberato; Krahne, Roman; Arciniegas, Milena P.
• Is Part Of: Nanoscale. Volume 13:Issue 7(2021)
• Page Start: 3948
• Page End: 3956
• Publication Date: 2021-02-15
• Subjects: Nanoscience -- Periodicals; Nanotechnology -- Periodicals; 620.505
• DOI: 10.1039/d0nr08043h
• Languages: English
• ISSNs: 2040-3364

Abstract

Abstract : The optical anisotropy of layered perovskites is exploited in flexible free-standing polymer films through multiple stretch/release cycles at low tensile stress, to enhance the emission intensity of the resulting composites. Abstract : The synergy between the organic component of two-dimensional (2D) metal halide layered perovskites and flexible polymers offers an unexplored window to tune their optical properties at low mechanical stress. Thus, there is a significant interest in exploiting their PL anisotropy by controlling their orientation and elucidating their interactions. Here, we apply this principle to platelet structures of micrometre lateral size that are synthesized in situ into free-standing polymer films. We study the photoluminescence of the resulting films under cyclic mechanical stress and observe an enhancement in the emission intensity up to ∼2.5 times along with a switch in the emission profile when stretching the films from 0% to 70% elongation. All the films recovered their initial emission intensity when releasing the stress throughout ca. 15 mechanical cycles. We hypothesize a combined contribution from reduced reabsorption, changes on in-plane and out-of-plane dipole moments that stem from different orientation of the platelets inside the film, and relative sliding of platelets within oriented stacks while stretching the films. Our results reveal how low-mechanical stress affects 2D layered perovskite aggregation and orientation, an open pathway toward the design of strain-controlled emission.