Kinetics and Mechanism of Oxidation of Benzyl Alcohol by Benzimidazolium Fluorochromate. Issue 4 (2008)
- Record Type:
- Journal Article
- Title:
- Kinetics and Mechanism of Oxidation of Benzyl Alcohol by Benzimidazolium Fluorochromate. Issue 4 (2008)
- Main Title:
- Kinetics and Mechanism of Oxidation of Benzyl Alcohol by Benzimidazolium Fluorochromate
- Authors:
- Dharmaraja, J.
Krishnasamy, K.
Shanmugam, M. - Abstract:
- Abstract : The kinetics of oxidation of benzyl alcohol (BzOH) by benzimidazolium fluorochromate (BIFC) has been studied in 50% aqueous acetic acid medium at 308 K. The reaction is first order with respect to [oxidant] and [benzyl alcohol]. The reaction is catalysed by hydrogen ions. The decrease in dielectric constant of the medium increases the rate of the reaction. Addition of sodium perchlorate increases the rate of the reaction appreciably. No polymerization with acrylonitrile. The reaction has been conducted at four different temperature and the activation parameters were calculated. From the observed kinetic results a suitable mechanism was proposed.
- Is Part Of:
- E-Journal of Chemistry. Volume 5:Issue 4(2008)
- Journal:
- E-Journal of Chemistry
- Issue:
- Volume 5:Issue 4(2008)
- Issue Display:
- Volume 5, Issue 4 (2008)
- Year:
- 2008
- Volume:
- 5
- Issue:
- 4
- Issue Sort Value:
- 2008-0005-0004-0000
- Page Start:
- 754
- Page End:
- 760
- Publication Date:
- 2008
- Subjects:
- Benzyl alcohol -- Kinetics and mechanism -- Oxidation -- Benzimidazolium fluorochromate
- DOI:
- 10.1155/2008/426508 ↗
- Languages:
- English
- ISSNs:
- 0973-4945
- Deposit Type:
- Legaldeposit
- View Content:
- Available online (eLD content is only available in our Reading Rooms) ↗
- Physical Locations:
- British Library HMNTS - ELD Digital store
- Ingest File:
- 15820.xml