Spectrophotometric Study of Adduct Formation Between [Co(Salen)PPh3]ClO4.H2O and [Co(7, 7'-Dimethylsalen)PPh3]ClO4.H2O with Amines Donors in Acetonitrile. Issue 4 (2010)
- Record Type:
- Journal Article
- Title:
- Spectrophotometric Study of Adduct Formation Between [Co(Salen)PPh3]ClO4.H2O and [Co(7, 7'-Dimethylsalen)PPh3]ClO4.H2O with Amines Donors in Acetonitrile. Issue 4 (2010)
- Main Title:
- Spectrophotometric Study of Adduct Formation Between [Co(Salen)PPh3]ClO4.H2O and [Co(7, 7'-Dimethylsalen)PPh3]ClO4.H2O with Amines Donors in Acetonitrile
- Authors:
- Niad, Mahmood
Mohammadi, Khosro
Asadi, Mozaffar - Abstract:
- Abstract : The equilibrium quotient of the adduct formation of [Co(Salen)PPh3 ]ClO4 .H2 O and [Co(7, 7'-dimethylSalen)PPh3 ]ClO4 .H2 O, as acceptor with amines donors are studied by spectrophotometer. Thermodynamics of these pentacoordinate cobalt(III) Schiff-base complexes have been examined with n -butylamine, sec -butylamine, tert -butylamine, benzylamine and diethylamine in constant ionic strength of 0.1 M sodium perchlorate and acetonitrile solvent at room temperature. We aimed to investigate the effects of different electronic and steric situations of donor and acceptor by comparing their equilibrium quotient for any adduct.
- Is Part Of:
- E-Journal of Chemistry. Volume 7:Issue 4(2010)
- Journal:
- E-Journal of Chemistry
- Issue:
- Volume 7:Issue 4(2010)
- Issue Display:
- Volume 7, Issue 4 (2010)
- Year:
- 2010
- Volume:
- 7
- Issue:
- 4
- Issue Sort Value:
- 2010-0007-0004-0000
- Page Start:
- 1421
- Page End:
- 1425
- Publication Date:
- 2010
- Subjects:
- Thermodynamic -- Cobalt Schiff-base -- Adduct -- Equilibrium quotient
- DOI:
- 10.1155/2010/320126 ↗
- Languages:
- English
- ISSNs:
- 0973-4945
- Deposit Type:
- Legaldeposit
- View Content:
- Available online (eLD content is only available in our Reading Rooms) ↗
- Physical Locations:
- British Library HMNTS - ELD Digital store
- Ingest File:
- 15821.xml