Multifunctional layer-perovskite oxide La2-xCexCuO4 for solid oxide fuel cell applications. (26th February 2021)

• Record Type: Journal Article
• Authors: Liu, Qing; Xiao, Ziwei; Xie, Han; Gao, Jinle; Yuan, Menghui; Dong, Wenjing
• Is Part Of: International journal of hydrogen energy. Volume 46:Number 15(2021)
• Page Start: 9818
• Page End: 9825
• Publication Date: 2021-02-26
• Subjects: Layer-perovskite oxide -- La2-xCexCuO4 -- Multifunctionality -- SOFC; Hydrogen as fuel -- Periodicals; Hydrogène (Combustible) -- Périodiques; Hydrogen as fuel; Periodicals; 665.81
• DOI: 10.1016/j.ijhydene.2020.06.063
• Languages: English
• ISSNs: 0360-3199

Abstract

Abstract: Materials are always among the first considerations to the development of low temperature solid oxide fuel cells (SOFCs). In this study, we investigate the multifunctionality of a layer-perovskite oxide La2-x Cex CuO4 (LCCO) for its applications in SOFC as cathode, anode and electrolyte. The performances of the LCCO cathode and anode fuel cells are characterized by I–V–P and electrochemical impedance spectra (EIS). Results suggest that LCCO is a good cathode material and it can also deliver impressive anode performance. Though LCCO is noticed to be reduced by H2 in the anode, the cell performance is relatively stable under multiple times of operation. The existing of ceria and reduced Cu in it may be a reason for its anode catalytic activation. For the application in electrolyte, LCCO is mixed with ionic conductor Ce0.8 Sm0.2 O2-δ (SDC) in different weight ratios. Differences in power output and open circuit voltage for the cells containing various ratios of LCCO under normal and reverse operation conditions are highlighted. The electronic conductivity of LCCO doesn't bring in electronic leakage if it is kept in a certain range. The multifunctionality of LCCO would enable it to be potentially applied in single layer fuel cell to simplify the structure and fabrication process of SOFC. Highlights: The multi-functionality of LCCO is developed. The investigation of anode catalytic activity of LCCO. Discussing electronic leakage from peak OCV and its stability.