Redox mediator assists electron transfer in lithium–sulfur batteries with sulfurized polyacrylonitrile cathodes. Issue 1 (14th December 2020)

• Record Type: Journal Article
• Authors: Zhao, Chang‐Xin; Chen, Wei‐Jing; Zhao, Meng; Song, Yun‐Wei; Liu, Jia‐Ning; Li, Bo‐Quan; Yuan, Tongqi; Chen, Cheng‐Meng; Zhang, Qiang; Huang, Jia‐Qi
• Is Part Of: EcoMat. Volume 3:Issue 1(2021)
• Page Start: n/a
• Page End: n/a
• Publication Date: 2020-12-14
• Subjects: electron transfer -- energy storage -- lithium–sulfur batteries -- redox mediator -- sulfurized polyacrylonitrile; Materials -- Environmental aspects -- Periodicals; Clean energy -- Periodicals; 621.042
• DOI: 10.1002/eom2.12066
• Languages: English
• ISSNs: 2567-3173

Abstract

Abstract: The development of next‐generation high‐energy‐density batteries requires advanced electrode materials. Sulfurized polyacrylonitrile (SPAN) is considered a promising sulfur cathode with the merits of high specific capacity and long cycling stability for high‐performance lithium–sulfur (Li–S) batteries. Nevertheless, the practical performances of SPAN cathodes are severely limited by the unfavorable electron accessibility due to the relatively low intrinsic conductivity and large particle size. Herein, a redox mediation strategy is proposed to accelerate the electron transfer processes in working Li–S batteries with SPAN cathodes. Specifically, a quinone‐based redox mediator is introduced to provide an additional redox pathway with strengthened interfacial kinetics. The redox mediator assisted SPAN cathodes exhibit higher specific capacity, improved rate performance, reduced polarization, and longer cycling lifespan with both ether‐based and carbonate‐based electrolyte. This work demonstrates the feasibility of redox mediation to promote the electron accessibility for high‐performance Li–S batteries with SPAN cathodes. Abstract : A redox mediation strategy is proposed to strengthen the interfacial kinetics of lithium–sulfur batteries with sulfurized polyacrylonitrile (SPAN) cathodes by introducing a quinone‐based redox mediator to provide an additional redox pathway. The redox mediated SPAN cathodes exhibit higher specific capacity, improved rate performance, and reduced polarization in both ether‐based and carbonate‐based electrolyte system. This work demonstrates the feasibility of redox mediation to promote the electron accessibility for Li–S batteries with SPAN cathodes.