Tobacco‐Stem‐Derived Nitrogen‐Enriched Hierarchical Porous Carbon for High‐Energy Supercapacitor. Issue 4 (21st January 2021)

• Record Type: Journal Article
• Authors: Wang, Hefang; Yang, Lijia; Liu, Guanghui; Li, Manhua
• Is Part Of: ChemistrySelect. Volume 6:Issue 4(2021)
• Page Start: 532
• Page End: 537
• Publication Date: 2021-01-21
• Subjects: tobacco stem -- nitrogen enriched -- hierarchical porous carbons -- supercapacitor; Chemistry -- Periodicals; 540.5
• DOI: 10.1002/slct.202004193
• Languages: English
• ISSNs: 2365-6549

Abstract

Abstract: Nitrogen enriched hierarchical porous carbons with high specific surface (SSA) area and well‐connected pore structure are highly desirable for supercapacitor electrode materials. Herein, nitrogen enriched hierarchical porous carbon (NHPC) was prepared by pre‐carbonization of tobacco stems and activation by KHCO3 . The as‐prepared NHPC‐800 exhibits high SSA (2691 m 2 g −1 ) and high proportion of mesopore (76.5 %). NHPC‐800 also shows high nitrogen content of 1.4 %. Benefited from improved pore structure and chemical composition, the obtained NHPC‐800 delivered a high capacitance of 252.9 F g −1 at 0.5 A g −1 and 189.1 F g −1 at 20 A g −1 in 6 M KOH. Additionally, the symmetric supercapacitor exhibits a high energy density of 7.8 W h kg −1 and good cycle stability with 92.6 % capacitance retention after 6000 charge/discharge cycles in 1 M Na2 SO4 electrolyte. The good electrochemical performance makes NHPC‐800 a potential electrode material for supercapacitor. Abstract : Tobacco stems derived nitrogen enriched hierarchical porous carbon (NHPC) was prepared by pre‐carbonization and activation by KHCO3 . NHPC‐800 exhibits good electrochemical performance in 6 M KOH and 1 M Na2 SO4 electrolyte. The good performance was attributed to high SSA (2691 m 2 g −1 ), well‐connected pore structure and high nitrogen content (1.4 %).