Colored emitters with silica-embedded perovskite nanocrystals for efficient daytime radiative cooling. (January 2021)

• Record Type: Journal Article
• Authors: Son, Soomin; Jeon, Sanghyun; Chae, Dongwoo; Lee, Sang Yeop; Liu, Yuting; Lim, Hangyu; Oh, Soong Ju; Lee, Heon
• Is Part Of: Nano energy. Volume 79(2021)
• Publication Date: 2021-01
• Subjects: Colored emitter -- Daytime radiative cooling -- Broadband mid-IR emitter -- Perovskite nanocrystal -- High photoluminescence quantum yields; Nanoscience -- Periodicals; Nanotechnology -- Periodicals; Nanostructured materials -- Periodicals; Power resources -- Technological innovations -- Periodicals; Nanoscience; Nanostructured materials; Nanotechnology; Power resources -- Technological innovations; Periodicals; 621.042
• DOI: 10.1016/j.nanoen.2020.105461
• Languages: English
• ISSNs: 2211-2855

Abstract

Abstract: Daytime radiative cooling is an innovative way to counter the temperature increase caused by solar exposure inside buildings, cars, and industries without consuming energy. To improve the radiative cooling performance, the light-to-heat energy conversion through solar reflection should be minimized, while the heat radiation in the wavelength range of 8–13 µm (atmospheric window) should be maximized. In this work, colored emitters for daytime radiative cooling are fabricated with silica-embedded perovskite nanocrystals, which can be colored with high light-to-photon conversion in the solar spectrum instead of light-to-heat conversion, and coated onto a highly mid-IR-radiative white emitter. The fabricated white, green, and red emitters for daytime radiative cooling exhibit sub-ambient cooling temperatures of 4.2, 3.6, and 1.7 °C, respectively, in outdoor measurements. Additionally, the enhancement of the daytime cooling performance by the light-photon conversion is proven through the comparison experiments and numerical calculation. These colored emitters for radiative cooling are more aesthetically pleasing than conventional white- and metallic-colored surface emitters, and are expected to diversify the applications for daytime radiative cooling. Graphical Abstract: This research is the colored mid-IR emitters with silica-embedded perovskite nanocrystals for daytime radiative cooling, which are more aesthetically pleasing than conventional white and metallic colored surface emitters. And, the enhancement of the daytime cooling performance by the light-photon conversion is proven through the comparison experiments and numerical calculation. ga1 Highlights: The colored mid-IR emitters for daytime radiative cooling were fabricated using SiO2 -embedded perovskite nanocrystals (NCs). Perovskite NCs have high PLQY, resulting in efficient daytime radiative cooling by light-to-photon conversion. The white, green and red colored emitters showed sub- or near- ambient cooling of 4.2 ℃, 3.6 ℃ and 1.7 ℃ during the daytime. The developed colored emitters show the efficient outdoor cooling performance than commercial painted emitters.