Development of Nitrogen-Doped Carbon Catalysts Using Melamine-Based Polymer as a Nitrogen Precursor for the Oxygen Reduction Reaction. Issue 7 (11th April 2015)

• Record Type: Journal Article
• Authors: Lee, Woong Hee; Lee, Dong Wook; Kim, Hansung
• Is Part Of: Journal of the Electrochemical Society. Volume 162:Issue 7(2015)
• Page Start: F744
• Page End: F749
• Publication Date: 2015-04-11
• Subjects: Nitrogen doped carbon -- Non-precious catalysts -- Oxygen reduction reaction; Electrochemistry -- Periodicals; 541.3705
• DOI: 10.1149/2.0571507jes
• Languages: English
• ISSNs: 0013-4651

Abstract

Abstract : Nitrogen-doped carbon catalysts for the oxygen reduction reaction (ORR) were synthesized using the pyrolysis of melamine-based polymer coated carbon black in the presence of cobalt. The linear sweep voltammogram that was recorded in an alkaline solution shows that the ORR activity of the nitrogen-doped carbon catalysts increases significantly close to that of Pt/C when a polymerized melamine is used as a nitrogen precursor instead of a melamine monomer. From the XPS-N 1s analysis, the introduction of the melamine-based polymer positively contributes to the nitrogen doping content and formation of a graphitic-N and pyridinic-N, which is known to be an active site for the ORR. Therefore, based on the quantitative analysis of the experimental results, melamine-based polymer is a promising precursor of nitrogen-doped carbon catalysts for ORR catalysts.