PEO‐b‐PS Block Copolymer Templated Mesoporous Carbons: A Comparative Study of Nitrogen and Sulfur Doping in the Oxygen Reduction Reaction to Hydrogen Peroxide. Issue 3 (3rd December 2020)

• Record Type: Journal Article
• Authors: Perazzolo, Valentina; Daniel, Giorgia; Brandiele, Riccardo; Picelli, Luca; Rizzi, Gian Andrea; Isse, Abdirisak Ahmed; Durante, Christian
• Is Part Of: Chemistry. Volume 27:Issue 3(2021)
• Page Start: 1002
• Page End: 1014
• Publication Date: 2020-12-03
• Subjects: carbon materials -- hydrogen peroxide -- nitrogen doped carbon -- oxygen reduction -- SARA-ATRP; Chemistry -- Periodicals; 540
• DOI: 10.1002/chem.202003355
• Languages: English
• ISSNs: 0947-6539

Abstract

Abstract: Carbon materials slightly doped with heteroatoms such as nitrogen (N‐RFC) or sulfur (S‐RFC) are investigated as active catalysts for the electrochemical bielectronic oxygen reduction reaction (ORR) to H2 O2 . Mesoporous carbons with wide, accessible pores were prepared by pyrolysis of a resorcinol‐formaldehyde resin using a PEO‐b‐PS block copolymer as a sacrificial templating agent and the nitrogen and sulfur doping were accomplished in a second thermal treatment employing 1, 10‐phenanthroline and dibenzothiophene as nitrogen and sulfur precursors, respectively. The synthetic strategy allowed to obtain carbon materials with very high surface area and mesopore volume without any further physicochemical post treatment. Voltammetric rotating ring‐disk measurements in combination with potentiostatic and galvanostatic bulk electrolysis measurements in 0.5 m H2 SO4 demonstrated a pronounced effect of heteroatom doping and mesopores volume on the catalytic activity and selectivity for H2 O2 . N‐RFC electrode was employed as electrode material in a 45 h electrolysis showing a constant H2 O2 production of 298 mmol g −1 h −1 (millimoles of H2 O2 divided by mass of catalyst and electrolysis time), with a faradic efficiency (FE) up to 61 % and without any clear evidence of degradation. The undoped carbon RFC showed a lower production rate (218 mmol g −1 h −1 ) but a higher FE of 76 %, while the performances drastically dropped when S‐RFC (production rate 11 mmol g −1 h −1 and FE=39 %) was used. Abstract : The PEO‐b‐PS block copolymer prepared by SARA‐ATRP was employed for the soft template synthesis of nitrogen and sulfur carbon materials with very high surface area (840–1350 m 2 g ‐1 ). N‐RFC showed superior catalytic activity and H2 O2 selectivity due to the fundamental role of mesopore, which not only favor the reagent and products mass transport but also host accessible nitrogen active sites.