CO release from Mn(i)-based photoCORMs with single photons in the phototherapeutic region. Issue 9 (18th January 2021)

• Record Type: Journal Article
• Authors: Stenger-Smith, Jenny; Chakraborty, Indranil; Ouattara, Ramatoulaye; Sameera, W. M. C.; Rue, Kelly; Mascharak, Pradip
• Is Part Of: Chemical communications. Volume 57:Issue 9(2021)
• Page Start: 1101
• Page End: 1104
• Publication Date: 2021-01-18
• Subjects: Chemistry -- Periodicals; 540
• DOI: 10.1039/d0cc07405e
• Languages: English
• ISSNs: 1359-7345

Abstract

Abstract : New Mn(i )-based photoCORMs with a fac -{Mn(CO)3 } moiety exhibit facile CO release upon simple exposure to light within the phototherapeutic region (no two photon excitation required). Abstract : Both the instrumentation required for two photon excitation (TPE) and tissue damage possibility by high intensity laser lights could impede TPE-induced CO delivery in hospital settings. Herein we report two Mn(i )-based photoCORMs with a fac -{Mn(CO)3 } moiety that exhibit facile CO release upon simple exposure to light within the phototherapeutic region (no TPE required).