Slow magnetic relaxation in structurally similar mononuclear 8-coordinate Fe(ii) and Fe(iii) compounds. Issue 6 (23rd December 2020)

• Record Type: Journal Article
• Authors: Su, Qian-Qian; Yuan, Qiong; Wu, Xiao-Fan; Chen, Si-Huai; Xiang, Jing; Jin, Xin-Xin; Wang, Li-Xin; Wang, Bing-Wu; Gao, Song; Lau, Tai-Chu
• Is Part Of: Chemical communications. Volume 57:Issue 6(2021)
• Page Start: 781
• Page End: 784
• Publication Date: 2020-12-23
• Subjects: Chemistry -- Periodicals; 540
• DOI: 10.1039/d0cc07004a
• Languages: English
• ISSNs: 1359-7345

Abstract

Abstract : A pair of structurally-similar and stable 8-coordinate high-spin Fe(ii ) and Fe(iii ) compounds have been obtained. Both compounds exhibit field-induced slow magnetic relaxation behaviour. Abstract : A pair of structurally-similar and stable 8-coordinate high-spin Fe(ii ) and Fe(iii ) compounds have been obtained. Both compounds exhibit field-induced slow magnetic relaxation behaviour. The Fe(iii ) compound represents the first example of 8-coordinate Fe(iii ) single-molecule magnets (SMM).