Multiple chiroptical switches and logic circuit based on salicyl‒ imine‒chitosan hydrogel. (1st April 2021)

• Record Type: Journal Article
• Authors: Liu, Changxia; Dong, Cuifang; Liu, Shuheng; Yang, Yang; Zhang, Zhichao
• Is Part Of: Carbohydrate polymers. Volume 257(2021)
• Publication Date: 2021-04-01
• Subjects: Chitosan hydrogel -- Supramolecular chirality -- Chiroptical switch -- Logic gate; Polysaccharides -- Periodicals; Polysaccharides -- Periodicals; Polysaccharides -- Périodiques; Electronic journals; 547.78
• DOI: 10.1016/j.carbpol.2020.117534
• Languages: English
• ISSNs: 0144-8617

Abstract

Highlights: Chirality transformation and amplification was realized in chitosan hydrogel. The multiple chiroptical switches were fabricated basing on the external stimuli. Chiral logic gates and logic circuit were successfully designed. Abstract: A chitosan-based chiral hydrogel was fabricated by grafting achiral salicylaldehyde (SA) on chitosan chains, followed by supramolecular assembly (CS-SA hydrogel hereafter). The structures and properties of the CS-SA hydrogel were characterized and investigated. The results indicated that the swelling ability of the CS-SA hydrogel depended on the medium pH and crosslinking degree. Circular dichroism measurements revealed that the chiral information of the chitosan was successfully transcribed to the achiral salicylic chromophores through imine bonds. Chiroptical switches based on acid-base responses of the imine bond and the OH fragment of SA and the swelling properties of the CS-SA hydrogel were fabricated, which is first reported for a chitosan-based hydrogel. In addition, a gel film showed good fatigue resistance under external stimuli. IMPLICATION, INHIBIT, and PASS logic gates and a logic circuit based on the chiroptical switches were successfully designed. This study suggests a new method of constructing biobased chiral functional materials.