Editors' Choice—Electrochemically Active Surface Area Measurement of Aged Pt Alloy Catalysts in PEM Fuel Cells by CO Stripping. Issue 2 (13th December 2016)

• Record Type: Journal Article
• Authors: Garrick, Taylor R.; Moylan, Thomas E.; Carpenter, Michael K.; Kongkanand, Anusorn
• Is Part Of: Journal of the Electrochemical Society. Volume 164:Issue 2(2017)
• Page Start: F55
• Page End: F59
• Publication Date: 2016-12-13
• Subjects: CO stripping -- ECSA -- fuel cell -- PEMFC -- Pt alloy catalyst; Electrochemistry -- Periodicals; 541.3705
• DOI: 10.1149/2.0381702jes
• Languages: English
• ISSNs: 0013-4651

Abstract

Abstract : The use of hydrogen adsorption/desorption (HAD) is a convenient method to measure the Pt surface area of a catalyst. However, it was shown that electrochemical charges measured by this technique can underestimate the Pt surface area by up to a factor of two for small Pt nanoparticles or Pt alloy nanoparticles. Electrooxidation of CO, so-called CO stripping, has been shown to be more accurate. Yet measurements of CO stripping in MEAs are scarce, especially on high activity alloy catalysts. In this study we investigated CO stripping and the ratio between Pt surface areas measured by CO and by HAD on several Pt and Pt alloy catalysts. The effects on these measurements of temperature and catalyst aging by voltage cycling are discussed.