Front Cover: Mechanistic Studies on Photoinduced Catalytic Olefin Migration Reactions at the Pd(II) Centers of a Porous Crystal, Metal‐Macrocycle Framework (Chem. Asian J. 3/2021). Issue 3 (12th January 2021)

• Record Type: Journal Article
• Authors: Yonezawa, Hirotaka; Shiraogawa, Takafumi; Han, Mengying; Tashiro, Shohei; Ehara, Masahiro; Shionoya, Mitsuhiko
• Is Part Of: Chemistry, an Asian journal. Volume 16:Issue 3(2021)
• Page Start: 174
• Page End: 174
• Publication Date: 2021-01-12
• Subjects: mechanism -- metallacycles -- olefin migration -- palladium -- photoactivation; Chemistry -- Periodicals; 540.5
• DOI: 10.1002/asia.202001432
• Languages: English
• ISSNs: 1861-4728

Abstract

Abstract : One‐dimensional crystalline channels with well‐defined active metal centers hold great potential as heterogeneous catalysts. Herein, the results of a mechanistic study of photoinduced olefin migration reactions at palladium sites arranged on the channel ceiling of a porous metal‐macrocycle framework are described. Experimental and theoretical studies revealed that the olefin migration was catalyzed via an alkyl mechanism by in situ generated Pd‐H species on the channel ceiling through photoirradiation. More information can be found in the Full Paper by Mitsuhiko Shionoya et al.