Liquid-Phase Ion Gun for Local Acidification of Na2S Aqueous Solution and Local Sulfidation of Fe-Cr Alloy Surface. Issue 10 (18th July 2018)

• Record Type: Journal Article
• Authors: Fushimi, Koji; Nakatsuji, Satoshi; Lee, Jun-Seob; Kitagawa, Yuichi; Nakanishi, Takayuki; Hasegawa, Yasuchika; Baba, Kazuhiko; Tsuri, Shiro
• Is Part Of: Journal of the Electrochemical Society. Volume 165:Issue 10(2018)
• Page Start: C618
• Page End: C623
• Publication Date: 2018-07-18
• Subjects: H2S -- LPIG -- sulfidation; Electrochemistry -- Periodicals; 541.3705
• DOI: 10.1149/2.0851810jes
• Languages: English
• ISSNs: 0013-4651

Abstract

Abstract : Local sulfidation of Fe-Cr alloy surfaces was attempted by using a liquid-phase ion gun (LPIG), in which a platinum microelectrode was anodically polarized in the vicinity of the alloy surface in 0.1 M Na2 S aqueous solution. An increase in H + -concentration, namely local acidification, of the solution in the narrow space between the microelectrode and alloy surface successfully induced the formation of an H2 S-concentrated environment and resulted in local sulfidation of the Fe-Cr alloy surface. The degree of sulfidation was dependent on acidification conditions such as the microelectrode current, specimen electrode potential and Cr concentration of the alloy. The use of an LPIG enables a sulfidation test not only to restrict the amount of H2 S generated but also to evaluate sulfidation of a material surface quantitatively.