Impact of Temperature and Discharge Rate on the Aging of a LiCoO2/LiNi0.8Co0.15Al0.05O2 Lithium-Ion Pouch Cell. Issue 7 (5th May 2017)

• Record Type: Journal Article
• Authors: Wu, Yao; Keil, Peter; Schuster, Simon F.; Jossen, Andreas
• Is Part Of: Journal of the Electrochemical Society. Volume 164:Issue 7(2017)
• Page Start: A1438
• Page End: A1445
• Publication Date: 2017-05-05
• Subjects: aging detection -- blended cathode -- discharge rate -- lithium-ion cell -- low temperature; Electrochemistry -- Periodicals; 541.3705
• DOI: 10.1149/2.0401707jes
• Languages: English
• ISSNs: 0013-4651

Abstract

Abstract : This paper presents a lithium-ion battery aging study in which pouch cells comprising a LiCoO2 /LiNi0.8 Co0.15 Al0.05 O2 blended cathode and a graphite anode are examined. The study focuses on the impact of temperature and discharge rate on the cycle life of the tested cells. Compared to the aging behavior of other lithium-ion cells in the literature, the cells tested here are less sensitive to the discharge rate but more vulnerable to low temperature cycling. The vulnerability to low temperature mainly comes from cathode degradation, especially of the LiCoO2 component. This is identified by electrochemical impedance spectroscopy, differential voltage analysis and incremental capacity analysis. The cells are able to achieve 3000–5000 cycles before reaching a capacity fade of 20%, also at higher discharge rates up to 5C. All in all, the high discharge rate capability could be a general advantage of pouch cells due to less mechanical and thermal stress in their geometry. Furthermore, more attention should be paid to the cathode health in low temperature applications of lithium-ion cells containing layered oxides. This paper focuses mainly on non-invasive aging detection methods for lithium-ion cells. Post-mortem results will be published in a following paper.