Graphene/TiO2-Ag Based Composites Used as Sensitive Electrode Materials for Amaranth Electrochemical Detection and Degradation. Issue 8 (31st March 2018)

• Record Type: Journal Article
• Authors: Pogacean, Florina; Rosu, Marcela-Corina; Coros, Maria; Magerusan, Lidia; Moldovan, Marioara; Sarosi, Codruta; Porav, Alin-Sebastian; Staden, Raluca-Ioana Stefan-van; Pruneanu, Stela
• Is Part Of: Journal of the Electrochemical Society. Volume 165:Issue 8(2018)
• Page Start: B3054
• Page End: B3059
• Publication Date: 2018-03-31
• Subjects: amaranth -- electrochemical detection -- graphene; Electrochemistry -- Periodicals; 541.3705
• DOI: 10.1149/2.0101808jes
• Languages: English
• ISSNs: 0013-4651

Abstract

Abstract : Graphene/TiO2 -Ag based composites having various quantities of TiO2 -Ag nanoparticles (5, 10 or 15 wt%) were successfully prepared through a facile chemical-thermal route. The morphological and structural characteristics of the synthesized materials denoted GTA-5, GTA-10 and GTA-15 were investigated by TEM, XRD and FTIR techniques. The composites were used for the modification of three gold electrodes (Au/GTA-5, Au/GTA-10, Au/GTA-15) which were next employed in the electrochemical detection and degradation of amaranth (an azo dye model). The electrode with the best performance in terms of sensitivity was the Au/GTA-10 electrode. It had considerably larger sensitivity (24 mA/M), in comparison with that of Au/GTA-5 and Au/GTA-15 electrode (8 mA/M and 12 mA/M, respectively). The limit of detection was the same for all modified electrodes (LOD = 1 × 10 −7 M; S/N = 3). The Au/GTA-10 electrode was also tested at the electrochemical degradation of amaranth, from aqueous solutions. The degradation reaction followed a first order kinetics with a half-time of degradation of 203 minutes. The response characteristics of the proposed sensor made it a good candidate for integration in the Ubiquitous sensor's network for IOT.