Communication—Polyethylene/PBI Pore-Filling Composite Membrane for High Performance Vanadium Redox Flow Battery. Issue 14 (19th September 2019)

• Record Type: Journal Article
• Authors: Wei, Hao; Liu, Yimeng; Xu, Weiguo; Liu, Jianguo; Yan, Chuanwei; Che, Xuefu; Yang, Jingshuai; Tong, Jing; Xiao, Wei
• Is Part Of: Journal of the Electrochemical Society. Volume 166:Issue 14(2019)
• Page Start: A3207
• Page End: A3209
• Publication Date: 2019-09-19
• Subjects: Batteries -- Batteries - aqueous -- Energy Storage -- membrane -- polybenzimidazole -- vanadium redox flow battery; Electrochemistry -- Periodicals; 541.3705
• DOI: 10.1149/2.0271914jes
• Languages: English
• ISSNs: 0013-4651

Abstract

Abstract : A pore-filling proton exchange membrane is fabricated by combining a porous polyethylene (PE) substrate and polybenzimidazole (PBI) resin for vanadium redox flow batteries (VRFB). The PE substrate not only optimized the structure of the composite membrane, but also significantly reduces its cost (< 30$·m −2 ). Compared with Nafion212 and pure PBI membrane, PE/PBI composite membrane exhibits higher VRFB energy efficiency (88.62%–80.11%) in a current density range of 100–200 mA cm −2 . And within 150 cycles at 180 mA cm −2, the composite membrane maintains stable charge-discharge performance with slower capacity decay rate, indicating a promising membrane candidate for VRFBs.