Analysis and Simulation of One-Dimensional Transport Models for Lithium Symmetric Cells. Issue 15 (15th November 2019)

• Record Type: Journal Article
• Authors: Subramaniam, Akshay; Chen, Jerry; Jang, Taejin; Geise, Natalie R.; Kasse, Robert M.; Toney, Michael F.; Subramanian, Venkat R.
• Is Part Of: Journal of the Electrochemical Society. Volume 166:Issue 15(2019)
• Page Start: A3806
• Page End: A3819
• Publication Date: 2019-11-15
• Subjects: Batteries - Lithium -- Batteries -- Lithium -- Symmetric cells; Electrochemistry -- Periodicals; 541.3705
• DOI: 10.1149/2.0261915jes
• Languages: English
• ISSNs: 0013-4651

Abstract

Abstract : The main objective of this paper is to analyze transport models for lithium symmetric cells and arrive at an efficient model and code to simulate the same. Two one-dimensional models are considered. The first model uses the dilute solution Nernst–Planck equations in conjunction with the electroneutrality assumption (EN-NP model). For binary electrolytes, an analytical solution for electrolyte concentration is derived and compared with numerical solutions by an approximate finite volume method. The second approach relaxes the electroneutrality assumption by way of Poisson's equation for the electrostatic potential (PNP model). The computational difficulties of the PNP model are tackled using the approximate finite volume method, with demonstrated convergence characteristics even with bulk dimensions several orders of magnitude larger than the characteristic double layer size. A robust code is developed for the PNP model. The computationally efficient transport models can facilitate simulations, physical understanding, and analysis. This is illustrated by a case study in which these models are coupled with modified kinetic models, which are then parameterized with experimental voltage response data using a systems-level approach. The estimated parameters provide further insight into the electrochemical phenomena underpinning voltage transitions in symmetric cells.