Lithium-Ion Cells Assembled with Flexible Hybrid Membrane Containing Li+-Conducting Lithium Aluminum Germanium Phosphate. Issue 6 (15th March 2016)

• Record Type: Journal Article
• Authors: Kim, Seul-Ki; Jung, Yun-Chae; Kim, Duck-Hyun; Shin, Woo-Cheol; Ue, Makoto; Kim, Dong-Won
• Is Part Of: Journal of the Electrochemical Society. Volume 163:Issue 6(2016)
• Page Start: A974
• Page End: A980
• Publication Date: 2016-03-15
• Subjects: Cycling performance -- Hybrid membrane -- Inorganic electrolyte -- Lithium aluminum germanium phosphate -- Lithium-ion cell; Electrochemistry -- Periodicals; 541.3705
• DOI: 10.1149/2.0831606jes
• Languages: English
• ISSNs: 0013-4651

Abstract

Abstract : Hybrid membranes composed of 90 wt% Li + -conducting inorganic electrolyte (lithium aluminum germanium phosphate, LAGP) and 10 wt% poly(vinylidene fluoride-co-hexafluoropropylene) (P(VdF-co-HFP)) polymer were prepared in the form of a flexible thin film and directly formed on the as-prepared negative electrode. The lithium-ion cells assembled with the hybrid membrane exhibited superior cycling performance in terms of discharge capacity, capacity retention, rate capability and high temperature cycling stability, as compared to the cell with polypropylene separator and liquid electrolyte. The use of hybrid membranes allowed improve thermal properties compared to conventional polyolefin separator and use less amount of flammable liquid electrolyte, resulting in enhancement of thermal safety of the cell.