Carbon (sp3) tetrel bonding mediated BODIPY supramolecular assembly via unprecedented synergy of Csp3⋯N and Csp3⋯F pair interactions. Issue 2 (21st December 2020)

• Record Type: Journal Article
• Authors: Ayhan, Mehmet Menaf; Özcan, Emrah; Dedeoglu, Burcu; Chumakov, Yurii; Zorlu, Yunus; Coşut, Bünyemin
• Is Part Of: CrystEngComm. Volume 23:Issue 2(2021)
• Page Start: 268
• Page End: 272
• Publication Date: 2020-12-21
• Subjects: Crystals -- Periodicals; Crystal growth -- Periodicals; Crystallography -- Periodicals; Cristaux -- Périodiques; Cristaux -- Croissance -- Périodiques; Cristallographie -- Périodiques; 548
• DOI: 10.1039/d0ce01640c
• Languages: English
• ISSNs: 1466-8033

Abstract

Abstract : Here, we present the first example of sp 3 hybridized carbon centered (Csp 3 ) tetrel bonding mediated 3D BODIPY assembly via the exceptional synergy of Csp 3 ⋯N and Csp 3 ⋯F pair interactions. Abstract : Here, we present the first example of sp 3 hybridized carbon centered (Csp 3 ) tetrel bonding mediated 3D BODIPY assembly via the exceptional synergy of Csp 3 ⋯N and Csp 3 ⋯F pair interactions. The carbon tetrel bond interaction energies of Csp 3 ⋯N and Csp 3 ⋯F are amplified significantly as the size of the 1D chain grows from dimer to tetramer BODIPY units.