Rheological performance of film-forming solutions made from plasma-modified starches with different amylose/amylopectin content. (1st March 2021)

• Record Type: Journal Article
• Authors: Hernandez-Perez, Pablo; Flores-Silva, Pamela C.; Velazquez, Gonzalo; Morales-Sanchez, Eduardo; Rodríguez-Fernández, Oliverio; Hernández-Hernández, Ernesto; Mendez-Montealvo, Guadalupe; Sifuentes-Nieves, Israel
• Is Part Of: Carbohydrate polymers. Volume 255(2021)
• Publication Date: 2021-03-01
• Subjects: HMDSO Hexamethyldisiloxane; Plasma -- Film-forming solutions -- Viscoelasticity -- Creep-recovery behavior -- HMDSO coating; Polysaccharides -- Periodicals; Polysaccharides -- Periodicals; Polysaccharides -- Périodiques; Electronic journals; 547.78
• DOI: 10.1016/j.carbpol.2020.117349
• Languages: English
• ISSNs: 0144-8617

Abstract

Highlights: Amylose content and plasma treatment determine the rheology of FFS. HMDSO coating reduced the amylopectin diffusion from the remnant starch granules. Plasma treatment favored FFS with low viscosity. The rheological findings were useful to predict the functional properties of the films. Plasma-modified FFS promoted the formation of films with good hydrophobic behavior. Abstract: Normal and high amylose corn starches were modified using HMDSO plasma at different time treatments. Changes in functional properties of starch granule, film-forming solutions (FFS) and films were investigated. SEM analysis revealed HMDSO coating deposition on the granule surface, which limited the amylopectin leach out from the granules to the continuous matrix, affecting the rheological properties of the FFS. The amylopectin restriction resulted in a low reinforcement of the network decreasing the viscosity as indicated by n and k values. Also, a gel-like behavior (G′ > G″) was observed when the amylose and time treatment increased, suggesting that the matrix becomes less elastic with softer entanglement. This behavior was confirmed by creep test and Burger model parameters. The plasma treatments allowed obtaining FFS with low viscosity, suitable for developing soft and hydrophobic films with low flexibility, as indicated by the decrease of the maximum stress, Hencky strain and permeance values.