Evolution of Microstructural Disorder in Annealed Bismuth Telluride Nanowires. (1st March 2017)

• Record Type: Journal Article
• Authors: Erickson, Kristopher J.; Limmer, Steven J.; Yelton, W. Graham; Rochford, Caitlin; Siegal, Michael P.; Medlin, Douglas L.
• Is Part Of: ECS journal of solid state science and technology. Volume 6:Number 3(2017)
• Page Start: N3117
• Page End: N3124
• Publication Date: 2017-03-01
• Subjects: bismuth telluride -- crystal defects -- electrodeposition -- electron microscopy -- grain boundaries -- nanowires -- thermoelectric; Solid state chemistry -- Periodicals; Electronics -- Materials -- Periodicals; Electrochemistry -- Periodicals; 541.0421
• DOI: 10.1149/2.0181703jss
• Languages: English
• ISSNs: 2162-8777

Abstract

Abstract : Controlling the distribution of structural defects in nanostructures is important since such defects can strongly affect critical properties, including thermal and electronic transport. However, characterizing the defect arrangements in individual nanostructures is difficult because of the small length scales involved. Here, we investigate the evolution of microstructural disorder with annealing in electrochemically deposited Bi2 Te3 nanowires, which are of interest for thermoelectrics. We combine Convergent Beam Electron Diffraction (CBED) and Scanning Transmission Electron Microscopy (STEM) to provide the necessary spatial and orientational resolution. We find that despite their large initial grain sizes and strong { 11 2 ¯ 0 } crystallographic texturing, the as-deposited nanowires still exhibit significant intragranular orientational disorder. Annealing drives both grain growth and a significant reduction in the intragranular disorder. The results are discussed in the context of the existing understanding of the initial microstructure of electrodeposited materials and the understanding of annealing microstructures in both electrochemically deposited and bulk-deformed materials. This analysis highlights the importance of assessing both the grain size and intragranular disorder in understanding the microstructural evolution of individual nanostructures.