N-Eicosane-Fe3O4@SiO2@Cu microcapsule phase change material and its improved thermal conductivity and heat transfer performance. (15th January 2021)

• Record Type: Journal Article
• Authors: Do, Jeong Yeon; Son, Namgyu; Shin, Jongmin; Chava, Rama Krishna; Joo, Sang Woo; Kang, Misook
• Is Part Of: Materials & design. Volume 198(2021)
• Publication Date: 2021-01-15
• Subjects: Phase change material -- Microencapsulation -- Form-stable phase change material -- Thermal conductivity -- n-eicosane-Fe3O4@SiO2@Cu; Materials -- Periodicals; Engineering design -- Periodicals; Matériaux -- Périodiques; Conception technique -- Périodiques; Electronic journals; 620.11
• DOI: 10.1016/j.matdes.2020.109357
• Languages: English
• ISSNs: 0264-1275

Abstract

Abstract: This study focused on developing an efficient phase change material (PCM) with a stable shape that can be applied in a wide range of industries. To prevent leakage of the PCM liquid at a temperature above the melting point, we used an encapsulation method by making use of an interfacial polycondensation reaction, and attempted to develop a new PCM with excellent thermal conductivity and thermal energy storage capacity. In order to improve the functionality of the PCM in latent thermal storage applications, a magnetic material, Fe3 O4, was mixed with n -eicosane and a shape-stable phase change microcapsule with a silica shell was successfully prepared. In this study, we loaded Cu metal nanoparticles on the outer wall of the capsule with the aim of improving the thermal conductivity of the material for efficient heat transfer. The results indicated that the n -eicosane-Fe3 O4 @SiO2 @Cu microcapsule has excellent heat transfer ability owing to its high thermal conductivity and exhibits efficient thermal energy storage–release performance by suppressing supercooling. The n -eicosane-Fe3 O4 @SiO2 @Cu microcapsule showed an encapsulation efficiency ( E en ) of 61.48%, an energy storage efficiency ( E es ) of 61.47%, and a thermal storage capacity ( C es ) of 99.99%. Moreover, the multi-cycle differential scanning calorimetry scan showed excellent thermal reliability and shape stability, even in repetitive melting–cooling processes, suggesting that it is a promising PCM that can be used in industrial applications. Graphical abstract: Unlabelled Image Highlights: A magnetic microencapsulated PCM has been proposed for ease of recovery treatment. Cu metal NPs were used to improve thermal conductivity. The thermal conductivity of n -eicosane-Fe3 O4 @SiO2 @Cu was improved more than 3 times. The n -eicosane-Fe3 O4 @SiO2 @Cu showed high thermal reliability even after 200 cycles.