An experimentally validated heat and mass transfer model for wax deposition from flowing oil onto a cold surface. Issue 2 (30th October 2020)

• Record Type: Journal Article
• Authors: Mahir, Luqman Hakim Ahmad; Lee, Jieun; Fogler, H. Scott; Larson, Ronald G.
• Is Part Of: AIChE journal. Volume 67:Issue 2(2021)
• Page Start: n/a
• Page End: n/a
• Publication Date: 2020-10-30
• Subjects: heat transfer -- mass transfer -- mathematical modeling -- moving boundary problem -- wax deposition; Chemical engineering -- Periodicals; Génie chimique -- Périodiques; 660.28
• DOI: 10.1002/aic.17063
• Languages: English
• ISSNs: 0001-1541

Abstract

Abstract: A transport model is proposed for wax deposition onto a cold finger from flowing wax‐containing oils. The model solves transient energy and mass balances simultaneously for a reversible first‐order kinetic rate for precipitation of pseudo‐single‐component wax, and the effects of yield stress using a critical solid wax concentration to withstand flow‐induced stress at the deposit‐fluid interface. The model can predict the time evolution of the deposit thickness, and the spatial and temporal evolution of temperature and wax concentration as validated using cold finger experiments. It was found that for high wax content oils, deposit thickness growth is dominated by heat transfer. For low wax content oils that are unable to gel, the thickness growth is slow and accompanied by occasional sloughing. Regardless of the mechanism controlling the growth, mass transfer cannot be neglected as wax diffusion into the deposit continues to take place after the deposit has stopped growing.