A novel organic/inorganic composite solid electrolyte with functionalized layers for improved room‐temperature rate performance of solid‐state lithium battery. (9th July 2019)

• Record Type: Journal Article
• Authors: Chen, Hao; Jing, Mao‐xiang; Han, Chong; Yang, Hua; Hua, Song; Chen, Fei; Chen, Li‐Li; Zhou, Zu‐xu; Ju, Bo‐wei; Tu, Fei‐yue; Shen, Xiang‐qian; Qin, Shi‐biao
• Is Part Of: International journal of energy research. Volume 43:Number 11(2019)
• Page Start: 5912
• Page End: 5921
• Publication Date: 2019-07-09
• Subjects: composite solid electrolyte -- high filling of LLZTO -- interfacial functionalized layers -- rate performance -- room temperature -- solid‐state lithium battery; Power resources -- Periodicals; Power (Mechanics) -- Periodicals; Power resources -- Research -- Periodicals; 621.042
• DOI: 10.1002/er.4699
• Languages: English
• ISSNs: 0363-907X

Abstract

Summary: High ionic conductivity at room temperature (RT) and good ion transport capability at electrode/electrolyte interface are fundamental requirements for high‐rate solid‐state lithium batteries (SSBs). In this work, we designed a poly (propylene carbonate) (PPC)‐based organic/inorganic composite solid electrolyte (CSE) membrane with high filling of tantalum‐doped lithium lanthanum zirconium oxide (LLZTO) and functionalized layers for enhancing the RT rate performance of SSB. The synergistic effect of LLZTO and interfacial functionalized layers endows the NCM622/CSE/Li battery with high‐rate and cycling performances at RT. The SSB with 20% LLZTO‐filled solid electrolyte shows the initial capacities of 162.0, 148.5 and 130.1 mAh g −1 at 1C, 2C, and 3C respectively, with retention capacities of 115.6, 104, and 100.6 mAh g −1 after 150 cycles. This strategy for an organic/inorganic CSE is of great practical significance for the development of high‐rate SSBs. Abstract : A lithium lanthanum zirconium oxide (LLZTO)‐filled composite solid electrolyte membrane with functionalized layers was prepared. The synergistic effect of high filling LLZTO and graphite coating improves the ionic conductivity and interfacial compatibility. The NCM622/composite solid electrolyte (CSE) (20%)/Li solid‐state lithium battery can be charged/discharged at 3C and room temperature.