A functionalized metal organic framework-laden nanoporous polymer electrolyte for exceptionally stable lithium electrodeposition. Issue 99 (26th November 2020)

• Record Type: Journal Article
• Authors: Qing, Xia; Li, Jiarui; Wang, Zongtao; Chen, Mao; Lin, Jun; Lin, Xinrong
• Is Part Of: Chemical communications. Volume 56:Issue 99(2020)
• Page Start: 15533
• Page End: 15536
• Publication Date: 2020-11-26
• Subjects: Chemistry -- Periodicals; 540
• DOI: 10.1039/d0cc06265k
• Languages: English
• ISSNs: 1359-7345

Abstract

Abstract : A nanoporous MOF-laden polymer electrolyte mediated by an electronic effect shows remarkably high lithium electrodeposition stability over 1500 h and minimum polarization. Abstract : A nanoporous all-solid-state MOF-laden polymer electrolyte that is simply mediated by an electronic effect shows remarkably high lithium electrodeposition stability of hundreds of charge–discharge cycles and over 1500 operating hours, while maintaining a very small voltage polarization. This result is a significant improvement relative to conventional PEO and, when used in an all-solid-state battery (ASSB), this electrolyte enabled enhanced cycle life. This new all-solid-state electrolyte shows a promising rational design for the emerging microporous polymeric materials as novel SPEs in ASSBs.