Structural Insight in the Interfacial Effect in Ferroelectric Polymer Nanocomposites. Issue 49 (4th November 2020)

• Record Type: Journal Article
• Authors: Liu, Yang; Yang, Tiannan; Zhang, Bing; Williams, Teague; Lin, Yen‐Ting; Li, Li; Zhou, Yao; Lu, Wenchang; Kim, Seong H.; Chen, Long‐Qing; Bernholc, J.; Wang, Qing
• Is Part Of: Advanced materials. Volume 32:Issue 49(2020)
• Page Start: n/a
• Page End: n/a
• Publication Date: 2020-11-04
• Subjects: atomic force microscopy–infrared spectroscopy -- ferroelectrics -- filler–matrix interfaces -- interfacial effects -- polymer nanocomposites; Materials -- Periodicals; Chemical vapor deposition -- Periodicals; 620.11
• DOI: 10.1002/adma.202005431
• Languages: English
• ISSNs: 0935-9648

Abstract

Abstract: Both experimental results and theoretical models suggest the decisive role of the filler–matrix interfaces on the dielectric, piezoelectric, pyroelectric, and electrocaloric properties of ferroelectric polymer nanocomposites. However, there remains a lack of direct structural evidence to support the so‐called interfacial effect in dielectric nanocomposites. Here, a chemical mapping of the interfacial coupling between the nanofiller and the polymer matrix in ferroelectric polymer nanocomposites by combining atomic force microscopy–infrared spectroscopy (AFM–IR) with first‐principles calculations and phase‐field simulations is provided. The addition of ceramic fillers into a ferroelectric polymer leads to augmentation of the local conformational disorder in the vicinity of the interface, resulting in the local stabilization of the all‐ trans conformation (i.e., the polar β phase). The formation of highly polar and inhomogeneous interfacial regions, which is further enhanced with a decrease of the filler size, has been identified experimentally and verified by phase‐field simulations and density functional theory (DFT) calculations. This work offers unprecedented structural insights into the configurational disorder‐induced interfacial effect and will enable rational design and molecular engineering of the filler–matrix interfaces of electroactive polymer nanocomposites to boost their collective properties. Abstract : Using atomic force microscopy–infrared spectroscopy together with first‐principles calculations and phase field simulations, a spatial structure analysis of the filler–matrix interfaces in ferroelectric polymer nanocomposites is provided. The unprecedented insights into the interfacial coupling effect at the molecular level would enable interfacial engineering strategies to realize improved properties and unlock new functionalities of the nanocomposites.