Phenanthrenes/dihydrophenanthrenes: the selectivity controlled by different benzynes and allenes. Issue 96 (20th November 2020)
- Record Type:
- Journal Article
- Title:
- Phenanthrenes/dihydrophenanthrenes: the selectivity controlled by different benzynes and allenes. Issue 96 (20th November 2020)
- Main Title:
- Phenanthrenes/dihydrophenanthrenes: the selectivity controlled by different benzynes and allenes
- Authors:
- Yao, Liangliang
Fang, Bo
Hu, Qiong
Lei, Yu
Bao, Li
Hu, Yimin - Abstract:
- Abstract : A method for the intermolecular annulation of benzynes with allenes is disclosed. Abstract : A method for the intermolecular annulation of benzynes with allenes is disclosed. This protocol utilized allenes as an unconventional diene component for the selective synthesis of phenanthrenes and dihydrophenanthrenes under the control of different benzyne precursors, featuring high atom-economy and good functional group compatibility. Density functional theory (DFT) calculations reveal that different migratory routes of the aromatic C–H bond are crucial for the observed selectivity.
- Is Part Of:
- Chemical communications. Volume 56:Issue 96(2020)
- Journal:
- Chemical communications
- Issue:
- Volume 56:Issue 96(2020)
- Issue Display:
- Volume 56, Issue 96 (2020)
- Year:
- 2020
- Volume:
- 56
- Issue:
- 96
- Issue Sort Value:
- 2020-0056-0096-0000
- Page Start:
- 15185
- Page End:
- 15188
- Publication Date:
- 2020-11-20
- Subjects:
- Chemistry -- Periodicals
540 - Journal URLs:
- http://pubs.rsc.org/en/journals/journalissues/cc ↗
http://www.rsc.org/ ↗ - DOI:
- 10.1039/d0cc06300b ↗
- Languages:
- English
- ISSNs:
- 1359-7345
- Deposit Type:
- Legaldeposit
- View Content:
- Available online (eLD content is only available in our Reading Rooms) ↗
- Physical Locations:
- British Library DSC - 3139.350000
British Library DSC - BLDSS-3PM
British Library STI - ELD Digital store - Ingest File:
- 14934.xml