Facile cyclization of sodium aminodiboranate to construct a boron–nitrogen–hydrogen ring. Issue 46 (16th November 2020)

• Record Type: Journal Article
• Authors: Li, Huizhen; Ju, Mingyue; Kang, Jiaxin; Zhou, Ai-Ju; Guan, Hong-Yu; Austin, Douglas J.; Yue, Yanfeng
• Is Part Of: Dalton transactions. Volume 49:Issue 46(2020)
• Page Start: 16662
• Page End: 16666
• Publication Date: 2020-11-16
• Subjects: Chemistry, Inorganic -- Periodicals; Chemistry, Physical and theoretical -- Periodicals; Chemistry, Inorganic -- Periodicals; 546.05
• DOI: 10.1039/d0dt03398g
• Languages: English
• ISSNs: 1477-9226

Abstract

Abstract : One-step cyclization of aminodiboranate can be used to prepare aminodiborane efficiently, where the dihydrogen bond plays an important role. Abstract : A facile and efficient cyclization of sodium aminodiboranate to construct a boron–nitrogen–hydrogen ring is presented. This new strategy can be developed into a general method to prepare aminodiborane and its derivatives. Theoretical calculations show that a one-step cyclization mechanism is favored, where the dihydrogen bond plays an important role.