Axial Cl/Br atom-mediated CO2 electroreduction performance in a stable porphyrin-based metal–organic framework. Issue 94 (5th November 2020)

• Record Type: Journal Article
• Authors: Huang, Qing; Niu, Qian; Ma, Na-Na; Dong, Long-Zhang; Li, Shun-Li; Li, Dong-Sheng; Cai, Yue-Peng; Lan, Ya-Qian
• Is Part Of: Chemical communications. Volume 56:Issue 94(2020)
• Page Start: 14817
• Page End: 14820
• Publication Date: 2020-11-05
• Subjects: Chemistry -- Periodicals; 540
• DOI: 10.1039/d0cc06092e
• Languages: English
• ISSNs: 1359-7345

Abstract

Abstract : Two isostructural MOFs were utilized to reveal the influence of different halogen anions on ECR performance. The different performance mainly originates from the different abilities of adsorption and activation of CO2 by halogen anions. Abstract : Two isostructural MOFs with coordination of different halogen ions (Cl − and Br − ), namely NNU-17 and NNU-18, were utilized to reveal the influence of different electron-withdrawing halogen anions on ECR performance. The performance difference between them mainly originates from the different abilities of adsorption and activation of CO2 by halogen ions.