Collective photothermal effect of Al2O3‐supported spheroidal plasmonic Ru nanoparticle catalysts in the sunlight‐powered Sabatier reaction. Issue 22 (4th September 2020)

• Record Type: Journal Article
• Authors: Grote, Roos; Habets, Roberto; Rohlfs, Jelle; Sastre, Francesc; Meulendijks, Nicole; Xu, Man; Verheijen, Marcel A.; Elen, Ken; Hardy, An; Van Bael, Marlies K.; den Hartog, Tim; Buskens, Pascal
• Is Part Of: ChemCatChem. Volume 12:Issue 22(2020)
• Page Start: 5618
• Page End: 5622
• Publication Date: 2020-09-04
• Subjects: plasmon catalysis -- Sabatier reaction -- carbon dioxide -- sunlight -- collective photothermal effect; Catalysis -- Periodicals; 541.39505
• DOI: 10.1002/cctc.202000795
• Languages: English
• ISSNs: 1867-3880

Abstract

Abstract: Plasmon catalysis is an interesting technology concept for powering chemical processes with light. Here, we report the use of various Al2 O3 ‐supported Ru spheroidal nanoparticles as catalyst for the low‐temperature conversion of CO2 and H2 to CH4 (Sabatier reaction), using sunlight as energy source. At high loadings of Ru spheroidal nanoparticles (5.9 % w/w), we observe a sharp increase in the rate of the sunlight powered reaction when compared to the reaction in dark at the same catalyst bed temperature. Based on our results we exclude plasmon coupling as cause, and attribute the rate enhancement to collective photothermal heating of the Al2 O3 ‐supported Ru nanoparticles. Abstract : CO2 Reduction : Al2 O3 ‐supported plasmonic Ru nanoparticles efficiently catalyze the sunlight‐powered low‐temperature conversion of CO2 and H2 to CH4 (Sabatier reaction). The sharp rate increase at high Ru loadings in combination with experimental and theoretical studies indicate a collective photothermal heating that powers this reaction.