Response to Comment on "Detection of the Elusive Nitrogen‐Centered Radicals from Catalytic Hofmann–Löffler Reactions". Issue 40 (20th October 2020)

• Record Type: Journal Article
• Authors: Bosnidou, Alexandra E.; Duhamel, Thomas; Muñiz, Kilian
• Is Part Of: European journal of organic chemistry. Issue 40(2020)
• Page Start: 6368
• Page End: 6369
• Publication Date: 2020-10-20
• Subjects: Amination -- Amines -- EPR spectroscopy -- Pyrrolidines -- Radicals; Chemistry, Organic -- Periodicals; Organic compounds -- Synthesis -- Periodicals; Bioorganic chemistry -- Periodicals; Chemistry, Physical organic -- Periodicals; 547
• DOI: 10.1002/ejoc.202001088
• Languages: English
• ISSNs: 1434-193X

Abstract

Abstract : The initial steps of the catalytic Hofmann–Löffler reaction include the formation of the N ‐halogenated amine with further formation of a nitrogen‐centered radical. We had reported the presence and detection of a radical through EPR spectroscopy. Based on new data, we discuss the observed EPR signal. Abstract : The initial steps of the catalytic Hofmann–Löffler reaction include the formation of the N ‐halogenated amine with further formation of a nitrogen‐centered radical. We had reported the presence and detection of a radical through EPR spectroscopy. Based on new data, we discuss the observed EPR signal. Amination, Amines, EPR spectroscopy, Pyrrolidines, Radicals