Co3O4 on Fe, N Doped Bio‐Carbon Substrate for Electrocatalysis of Oxygen Reduction. Issue 40 (30th August 2020)

• Record Type: Journal Article
• Authors: Zhang, Wei; Shi, Jing; Duan, Mengting; Tong, Xiangzhi; Zhou, Dongcheng; Chen, Jiale; Guo, Xingmei; Zhang, Junhao; Kong, Qinghong; Cheng, Xiaofang
• Is Part Of: European journal of inorganic chemistry. Issue 40(2020)
• Page Start: 3869
• Page End: 3876
• Publication Date: 2020-08-30
• Subjects: Biomass -- Cobalt -- Doping -- Nanostructures -- Oxygen reduction reaction; Chemistry, Inorganic -- Periodicals; Organometallic chemistry -- Periodicals; Bioinorganic chemistry -- Periodicals; Solid state chemistry -- Periodicals; 546
• DOI: 10.1002/ejic.202000645
• Languages: English
• ISSNs: 1434-1948

Abstract

Abstract : Searching for efficient non‐noble metal electrocatalyst for oxygen reduction reaction (ORR) has become a hot topic in electrochemical field. Herein, duck blood containing heme (a type of ferriporphyrin) is carbonized and activated to obtain Fe, N doped carbon. The activated carbonized blood (a‐CB) exhibits an extremely high specific surface area of 2655 m 2 g – 1 . Then, Co3 O4 nanoparticles are loaded on the efficient substrate via hydrothermal method. The as obtained Co3 O4 /a‐CB composite exhibits good catalytic performance for ORR. The onset and half‐wave potentials are 0.95 and 0.77 V vs. RHE, respectively. These values are comparable to those of commercial Pt/C (20 wt.‐%) catalyst. What's more, Co3 O4 /a‐CB shows better durability and methanol tolerance than commercial Pt/C, making it a promising electrocatalyst for ORR. Compared to artificial porous heteroatom doped carbon materials, this work seeks raw materials from natural biomass waste to obtain efficient carbon substrate with both high porosity and Fe, N self‐doping feature for catalyst applications. Abstract : A Co3 O4 /a‐CB composite with high specific surface area was fabricated via activation and hydrothermal method using duck blood as Fe, N self‐doped carbon skeleton source. Efficient electrocatalytic performance for ORR with good stability and methanol tolerance has been achieved.