Μ-Nitrido-bridged iron phthalocyanine dimer bearing eight peripheral 12-crown-4 units and its methane oxidation activity. (4th November 2020)

• Record Type: Journal Article
• Authors: Yamada, Yasuyuki; Kura, Jyunichi; Toyoda, Yuka; Tanaka, Kentaro
• Is Part Of: New journal of chemistry. Volume 44:Number 44(2020)
• Page Start: 19179
• Page End: 19183
• Publication Date: 2020-11-04
• Subjects: Chemistry -- Periodicals; Chimie -- Périodiques; 540
• DOI: 10.1039/d0nj04601a
• Languages: English
• ISSNs: 1144-0546

Abstract

Abstract : A novel μ-nitrido-bridged iron phthalocyanine dimer with eight peripheral 12-crown-4 units was synthesized and its methane oxidation activity was investigated. Abstract : A novel μ-nitrido-bridged iron phthalocyanine dimer with eight peripheral 12-crown-4 units as an electron-donating substituent was synthesized and characterized. Examination of its methane oxidation activity in the presence of H2 O2 in an acidic aqueous solution suggested that the high-valent iron oxo species generated in situ was unstable and the transiently generated decomposed species showed methane oxidation activity via Fenton-type reaction.