Preparation and characterization of thermoresponsive poly(N‐isopropylacrylamide‐co‐N‐isopropylmethacrylamide) hydrogel materials for smart windows. Issue 6 (20th August 2020)

• Record Type: Journal Article
• Authors: Jang, Ji‐Won; Park, Jae‐Hyong; Kim, Il‐Jin; Sim, Jae‐Hak; Yu, Seung‐gun; Lee, Dong‐Jin; Lee, Young‐Hee; Park, Sang‐Hui; Kim, Han‐Do
• Is Part Of: Journal of applied polymer science. Volume 138:Issue 6(2021)
• Page Start: n/a
• Page End: n/a
• Publication Date: 2020-08-20
• Subjects: applications -- copolymers -- cross‐linking -- differential scanning calorimetry -- thermal properties; Polymers -- Periodicals; Polymerization -- Periodicals; 668.9
• DOI: 10.1002/app.49788
• Languages: English
• ISSNs: 0021-8995

Abstract

Abstract: In this study, a series of thermoresponsive cross‐linked copolymer poly [N‐isopropylacrylamide(NIPAm)‐co‐N‐isopropylmethacrylamide(NIPMAm)] (P‐M series samples: P‐M‐0, 10, 20, 30, 40, where numbers are co‐monomer contents) hydrogels were prepared by free radical polymerization using the main monomer N‐isopropylacrylamide (NIPAm), co‐monomer N‐isopropylmethacrylamide (NIPMAm), cross‐linking agent N, N‐methylenebisacrylamide, initiator (ammonium persulfate)/catalyst, and solvent water. In addition, a series of samples [P‐G series samples: P‐G‐0, 10, 20, 30, 40, where numbers are co‐solvent glycerol content) were prepared using P‐M‐40 as components and water/co‐solvent glycerol as a mixed solvent. The effects of co‐monomer NIPMAm and co‐solvent glycerol contents on the lower critical solution temperature (LCST)/freezing temperature and light transmittance as function of temperature of the prepared copolymer gels were investigated. The resulting thermoresponsive polymer gels had LCSTs in the range of 17.9 to 38.7°C and freezing points in the range of 6.3 to −38.5°C. These gels are suitable materials for smart windows that are responsive to various environmental conditions. Abstract : Two series of thermoresponsive (temperature‐responsive) co‐polyacrylamides hydrogel materials to be used for smart windows were prepared using water/glycerol as a mixed solvent. By investigating the effect of co‐monomer and glycerol content on LCST and freezing point of materials, it was confirmed that various materials with various LCSTs (17.9 ∼ 38.7°C) and freezing points (6.3 ∼ −38.5°C) can be obtained. It was found that these materials have applicability to smart windows in various temperature environments.