Dielectric and gas adsorption/desorption properties of x-Li(Pc) having one-dimensional channels surrounded by Pc˙− columns. Issue 44 (27th October 2020)

• Record Type: Journal Article
• Authors: Nishi, Miki; Hoshino, Norihisa; Noro, Shin-ichiro; Fujimoto, Hitoshi; Akutagawa, Tomoyuki; Matsuda, Masaki
• Is Part Of: CrystEngComm. Volume 22:Issue 44(2020)
• Page Start: 7528
• Page End: 7531
• Publication Date: 2020-10-27
• Subjects: Crystals -- Periodicals; Crystal growth -- Periodicals; Crystallography -- Periodicals; Cristaux -- Périodiques; Cristaux -- Croissance -- Périodiques; Cristallographie -- Périodiques; 548
• DOI: 10.1039/d0ce01157f
• Languages: English
• ISSNs: 1466-8033

Abstract

Abstract : A one-dimensional channel system x -Li(Pc), composed of π-radical Pc˙ −, was investigated. It was revealed that this channel surrounded by Li(Pc) columns is flexible, and gas adsorption/desorption measurements showed selective properties. Abstract : A one-dimensional channel system x -Li(Pc), composed of π-radical Pc˙ −, was investigated. Crystal structure analysis revealed that this channel surrounded by Li(Pc) columns is flexible, and gas adsorption/desorption measurements showed selective adsorption/desorption properties. Along with Li + motion, specific dielectric properties induced by a guest species within the channel were also observed.