Photocycloadditions in disparate chemical environments. Issue 90 (26th October 2020)

• Record Type: Journal Article
• Authors: Marschner, David E.; Kamm, Philipp W.; Frisch, Hendrik; Unterreiner, Andreas-Neil; Barner-Kowollik, Christopher
• Is Part Of: Chemical communications. Volume 56:Issue 90(2020)
• Page Start: 14043
• Page End: 14046
• Publication Date: 2020-10-26
• Subjects: Chemistry -- Periodicals; 540
• DOI: 10.1039/d0cc03911j
• Languages: English
• ISSNs: 1359-7345

Abstract

Abstract : We elucidate the wavelength dependence of a photocycloaddition by accessing action plots dependent on the reactivity relative to the number of absorbed photons and establish the effect of concentration and solvent on the reactivity. Abstract : We elucidate the wavelength dependence of a photocycloaddition by (i) accessing action plots dependent on the reactivity relative to the number of absorbed photons, (ii) establishing the effect on substrate concentration on photochemical reactivity and (iii) determining wavelength-dependent reactivity as a function of the solvent environment, comparing acetonitrile with dimethyl sulfoxide.