Aluminium complexes of salanol ligands: coordination chemistry and stereoselective lactide polymerization. Issue 88 (13th October 2020)
- Record Type:
- Journal Article
- Title:
- Aluminium complexes of salanol ligands: coordination chemistry and stereoselective lactide polymerization. Issue 88 (13th October 2020)
- Main Title:
- Aluminium complexes of salanol ligands: coordination chemistry and stereoselective lactide polymerization
- Authors:
- Hador, Rami
Lipstman, Sophia
Rescigno, Raffaella
Venditto, Vincenzo
Kol, Moshe - Abstract:
- Abstract : Aluminium complexes of the new salanol ligands give rise to all PLA tacticities by different stereocontrol mechanisms. Abstract : The tetradentate dianionic {ONNO}-type salanol ligands featuring phenolate and alcoholate arms and a chiral-bipyrrolidine core are introduced. The diastereoselectively-formed {ONNO}-Al-OBn complexes catalyze the ring-opening polymerization of rac -lactide and meso -lactide by either the dual stereocontrol or the chain-end stereocontrol mechanisms to give PLAs of all possible tacticities.
- Is Part Of:
- Chemical communications. Volume 56:Issue 88(2020)
- Journal:
- Chemical communications
- Issue:
- Volume 56:Issue 88(2020)
- Issue Display:
- Volume 56, Issue 88 (2020)
- Year:
- 2020
- Volume:
- 56
- Issue:
- 88
- Issue Sort Value:
- 2020-0056-0088-0000
- Page Start:
- 13528
- Page End:
- 13531
- Publication Date:
- 2020-10-13
- Subjects:
- Chemistry -- Periodicals
540 - Journal URLs:
- http://pubs.rsc.org/en/journals/journalissues/cc ↗
http://www.rsc.org/ ↗ - DOI:
- 10.1039/d0cc05957a ↗
- Languages:
- English
- ISSNs:
- 1359-7345
- Deposit Type:
- Legaldeposit
- View Content:
- Available online (eLD content is only available in our Reading Rooms) ↗
- Physical Locations:
- British Library DSC - 3139.350000
British Library DSC - BLDSS-3PM
British Library STI - ELD Digital store - Ingest File:
- 14696.xml