A delocalized cobaltoviologen with seven reversibly accessible redox states and highly tunable electrochromic behaviour. Issue 89 (22nd October 2020)
- Record Type:
- Journal Article
- Title:
- A delocalized cobaltoviologen with seven reversibly accessible redox states and highly tunable electrochromic behaviour. Issue 89 (22nd October 2020)
- Main Title:
- A delocalized cobaltoviologen with seven reversibly accessible redox states and highly tunable electrochromic behaviour
- Authors:
- Mansoor, Iram F.
Wozniak, Derek I.
Wu, Yilei
Lipke, Mark C. - Abstract:
- Abstract : Cobalt was found to mediate strong electronic coupling between two viologen-like redox-active ligands, providing electrochromic properties that are easily tuned by the applied redox potential. Abstract : Co II mediates electronic coupling between two N -Me-pyridinium-terpyridine ligands that are related to redox-active N, N -dialkyl-4, 4′-bipyridinium dications (viologens). Borderline Class II/III electronic delocalization imparts the cobaltoviologen complex with distinct electronic properties ( e.g., 7 accessible redox states) relative to those of viologens, leading to enhanced electrochromism.
- Is Part Of:
- Chemical communications. Volume 56:Issue 89(2020)
- Journal:
- Chemical communications
- Issue:
- Volume 56:Issue 89(2020)
- Issue Display:
- Volume 56, Issue 89 (2020)
- Year:
- 2020
- Volume:
- 56
- Issue:
- 89
- Issue Sort Value:
- 2020-0056-0089-0000
- Page Start:
- 13864
- Page End:
- 13867
- Publication Date:
- 2020-10-22
- Subjects:
- Chemistry -- Periodicals
540 - Journal URLs:
- http://pubs.rsc.org/en/journals/journalissues/cc ↗
http://www.rsc.org/ ↗ - DOI:
- 10.1039/d0cc05627h ↗
- Languages:
- English
- ISSNs:
- 1359-7345
- Deposit Type:
- Legaldeposit
- View Content:
- Available online (eLD content is only available in our Reading Rooms) ↗
- Physical Locations:
- British Library DSC - 3139.350000
British Library DSC - BLDSS-3PM
British Library STI - ELD Digital store - Ingest File:
- 14701.xml