Hydrogen production from formaldehyde steam reforming using recyclable NiO/NaF catalyst. (30th October 2020)

• Record Type: Journal Article
• Authors: Chu, Lin; Gu, Sasa; Jin, Qijie; Zhu, Pengfei; Shen, Yuesong; Li, Peiwen
• Is Part Of: International journal of hydrogen energy. Volume 45:Number 53(2020)
• Page Start: 28752
• Page End: 28763
• Publication Date: 2020-10-30
• Subjects: Hydrogen production -- Formaldehyde -- Recyclable NiO/NaF catalysts -- Steam reforming; Hydrogen as fuel -- Periodicals; Hydrogène (Combustible) -- Périodiques; Hydrogen as fuel; Periodicals; 665.81
• DOI: 10.1016/j.ijhydene.2020.07.223
• Languages: English
• ISSNs: 0360-3199

Abstract

Abstract: Harmless disposal of formaldehyde for hydrogen production is attractive in energy and environmental science. Herein, hydrogen production from formaldehyde steam reforming (FSR) using recyclable NiO/NaF was investigated, and the optimized 4 wt % catalyst exhibited 100% formaldehyde conversion, 104.9% H2 selectivity and excellent stability at 400 °C. The used catalysts can be easily recycled by water washing and pickling, and the activity of the regenerated catalyst is comparable to that of fresh one. We confirmed that FSR was a rapid surface reaction process, and the special contribution of NaF ensured the high activity of NiO/NaF with low specific surface areas. F ions in the carrier could activate the surface OH, which promoted adsorption and oxidation to reactants. Furthermore, the in situ DRIFTs study revealed that formate species (HCOO) was the key intermediate in formaldehyde steam reforming. Formaldehyde was first oxidized to HCOO and then decomposed into CO2 and H. Graphical abstract: Image 1 Highlights: NiO/NaF is active and stable in formaldehyde steam reforming for H2 production. The used NiO/NaF catalysts can be easily regenerated to the fresh level. Formaldehyde steam reforming over NiO/NaF is a fast surface reaction. Formate species is the key intermediate in formaldehyde steam reforming.