Development of a Correlated Fe‐Mn Crust Stratigraphy Using Pb and Nd Isotopes and Its Application to Paleoceanographic Reconstruction in the Atlantic. Issue 10 (13th October 2020)

• Record Type: Journal Article
• Authors: Josso, P.; Horstwood, M. S. A.; Millar, I. L.; Pashley, V.; Lusty, P. A. J.; Murton, B.
• Is Part Of: Paleoceanography and paleoclimatology. Volume 35:Issue 10(2020)
• Page Start: n/a
• Page End: n/a
• Publication Date: 2020-10-13
• Subjects: Pb‐Nd isotope -- Fe‐Mn crust -- Atlantic -- paleoceanography -- correlated stratigraphy; Paleoceanography -- Periodicals; Paleoclimatology -- Periodicals; 551.46
• DOI: 10.1029/2020PA003928
• Languages: English
• ISSNs: 2572-4517

Abstract

Abstract: Eight ferromanganese crust samples spanning the complete depth range of Tropic Seamount in the northeast Atlantic were analyzed for Pb and Nd isotopes to reconstruct water mass origin and mixing over the last 75 Ma. Pb isotopes were determined by laser ablation multicollector inductively coupled plasma mass spectrometer (LA‐MC‐ICP‐MS), which enables the rapid production of large, high spatial resolution data sets. This makes it possible to precisely correlate stratigraphy between different samples, compare contemporaneous layers, and create a composite record given the abundance of hiatuses in crusts. Pb and Nd isotope data show the influence of various oceanic and continental end‐members in the northeast Atlantic Ocean. This reflects its evolution from a restricted, isolated basins in the Late Cretaceous with influxes from the Tethys Ocean, to an increasingly well‐mixed, large‐scale basin, with a dominant Southern Ocean signature until the Miocene. Less radiogenic Nd isotope signatures suggest Labrador Sea Water influenced the northeast Atlantic basin as early as 17–15 Ma, flowing through a northern route such as the Charlie‐Gibbs Fracture Zone. Pb and Nd isotopes highlight the increasing influence of Saharan eolian dust input about 7 Ma, imparting a less radiogenic excursion to the binary mixing between North Atlantic water masses and riverine discharge from West and Central Africa. This highlights the influence of eolian dust input on the open ocean Pb and Nd budget and supports an early stage of North African aridification in the Late Miocene. This signature is overprinted about 3 Ma to the present by a strong North Atlantic Deep Water signature following the onset of Northern Hemisphere glaciation. Key Points: Rapid production of Pb isotope data via laser ablation allows creation of correlated stratigraphic framework for hydrogenetic Fe‐Mn crusts Pb‐Nd data over the last 75 Ma show evolution from restricted basin to open ocean circulation with influence from local continental masses Labrador Seawater is present in the east Atlantic basin since 17 Ma and aridification of North Africa can be traced back to 7 Ma