Mechanism of the oscillating chemiluminescence reaction in the luminol‐H2O2‐KSCN‐CuSO4‐NaOH system. Issue 12 (4th August 2020)

• Record Type: Journal Article
• Authors: Toki, Erika; Osaki, Shiori; Nakamura, Misato; Tsuoka, Kazuki; Samejima, Nobutoshi; Nakashima, Tetsuto; Abe, Rin; Oyama, Takahiro; Tsukiyama, Koichi
• Is Part Of: International journal of chemical kinetics. Volume 52:Issue 12(2020)
• Page Start: 907
• Page End: 917
• Publication Date: 2020-08-04
• Subjects: chemiluminescence -- luminol -- reaction mechanisms -- Runge‐Kutta method; Chemical kinetics -- Periodicals; 541.394
• DOI: 10.1002/kin.21409
• Languages: English
• ISSNs: 0538-8066

Abstract

Abstract: We conducted a simultaneous measurement of the potential of Cu 2+, oxidation‐reduction potential (ORP), and the chemiluminescence intensity in the luminol‐H2 O2 ‐KSCN‐CuSO4 ‐NaOH system. Two types of chemiluminescence were identified: a very faint continuous chemiluminescence and a strong oscillating chemiluminescence. The correlation between the potential of Cu 2+ and ORP was measured experimentally for the first time. The effect of the initial concentrations of Cu 2+ and H2 O2 on the overall chemiluminescence intensity and the oscillation frequency was investigated in detail. Time‐dependent concentration variation of the chemical species existing in the reaction system was calculated using a Runge‐Kutta method. Two elementary chemical reactions not considered previously were taken into consideration. The overall experimental behavior was well explainable with our simulation. Based upon the comparison of our simulation with the experiment, we proposed that the strong oscillating chemiluminescence was induced by the reaction of luminol with ·OS(O)CN.