A Double‐Passivation Water‐Based Galvanic Displacement Method for Reproducible Gram‐Scale Production of High‐Performance Platinum‐Alloy Electrocatalysts. (1st July 2019)

• Record Type: Journal Article
• Authors: Gatalo, Matija; Bele, Marjan; Ruiz‐Zepeda, Francisco; Šest, Ervin; Šala, Martin; Kamšek, Ana Rebeka; Maselj, Nik; Galun, Timotej; Jovanovič, Primož; Hodnik, Nejc; Gaberšček, Miran
• Is Part Of: Angewandte Chemie. Volume 131:Number 38(2019)
• Page Start: 13400
• Page End: 13404
• Publication Date: 2019-07-01
• Subjects: Doppelte Passivierung -- Galvanische Verdrängung -- Platinlegierungen -- Protonenaustauschmembran-Brennstoffzelle -- Sauerstoffreduktionsreaktion; Chemistry -- Periodicals; 540
• DOI: 10.1002/ange.201903568
• Languages: English
• ISSNs: 0044-8249

Abstract

Abstract: Preparation of large quantities of high‐performance supported Pt‐alloy electrocatalysts is crucial for the faster development and implementation of low‐temperature proton exchange membrane fuel cells (PEMFCs). One of the prospective nanofabrication synthesis methods is based on the galvanic displacement (GD) reaction. A facile, highly reproducible, gram scale, water‐based double passivation GD method is now presented for the synthesis of carbon‐supported Pt‐M nanoparticles (M=Cu, Ni, Co). It offers great flexibility over the catalyst design, such as the choice of the sacrificial metal (M), variation of the chemical composition of alloy, variation of total metal loading (Pt+M) on carbon support, or even variation of the carbon support itself. The obtained Pt‐alloy catalysts are several times more active compared to a Pt reference and exhibits better stability during accelerated degradation tests performed at 60 °C. Abstract : Galvanische Verdrängung (GD) ist eine Methode für die Nanofabrikation trägerfixierter Pt‐M‐NPs (M=Cu, Ni, Co). Ein einfacher Doppelpassivierungsansatz für die GD ist hoch reproduzierbar im Gramm‐Maßstab sowie wasserbasiert. Die Methode bietet große Flexibilität für das Katalysatordesign, darunter die Wahl des Opfermetalls (M), die Variation der Pt/M‐Zusammensetzung und der Gesamtmetallgehalt (Pt+M) auf dem Kohlenstoffträger.