Buchwald–Hartwig Amination of Nitroarenes. (22nd September 2017)
- Record Type:
- Journal Article
- Title:
- Buchwald–Hartwig Amination of Nitroarenes. (22nd September 2017)
- Main Title:
- Buchwald–Hartwig Amination of Nitroarenes
- Authors:
- Inoue, Fumiyoshi
Kashihara, Myuto
Yadav, M. Ramu
Nakao, Yoshiaki - Abstract:
- Abstract: The Buchwald–Hartwig amination of nitroarenes was achieved for the first time by using palladium catalysts bearing dialkyl(biaryl)phosphine ligands. These cross‐coupling reactions of nitroarenes with diarylamines, arylamines, and alkylamines afforded the corresponding substituted arylamines. A catalytic cycle involving the oxidative addition of the Ar−NO2 bond to palladium(0) followed by nitrite/amine exchange is proposed based on a stoichiometric reaction.
- Is Part Of:
- Angewandte Chemie. Volume 129:Number 43(2017)
- Journal:
- Angewandte Chemie
- Issue:
- Volume 129:Number 43(2017)
- Issue Display:
- Volume 129, Issue 43 (2017)
- Year:
- 2017
- Volume:
- 129
- Issue:
- 43
- Issue Sort Value:
- 2017-0129-0043-0000
- Page Start:
- 13492
- Page End:
- 13494
- Publication Date:
- 2017-09-22
- Subjects:
- Aminierungen -- C-N-Aktivierung -- Kreuzkupplungen -- Nitroarene -- Palladium
Chemistry -- Periodicals
540 - Journal URLs:
- http://onlinelibrary.wiley.com/ ↗
- DOI:
- 10.1002/ange.201706982 ↗
- Languages:
- English
- ISSNs:
- 0044-8249
- Deposit Type:
- Legaldeposit
- View Content:
- Available online (eLD content is only available in our Reading Rooms) ↗
- Physical Locations:
- British Library DSC - 0902.000000
British Library DSC - BLDSS-3PM
British Library HMNTS - ELD Digital store - Ingest File:
- 14504.xml